I know many slab houses can't be used for a CEE if is has a vapor barriers or insulation foam boards under it, but if there are footers that go down to the frost line like we have to have around here and they are poured concrete then it can be used if it has 20' of re-bar or copper wire in it located close to the bottom of the concrete, these footers are rarely vapor blocked or would have foam insulation board under them, I know in Florida most houses were slab and didn't have footers so many times we couldn't use the slab as a CEE.
In the case where you can't use the slab then you just install rods to either supplements the water line or if the water line is plastic then you might end up to only having the rods as your electrode system very common around here on houses with wells, Indiana still doesn't require a CEE if it wasn't made available before we get there, but I always try to set it up with the builder so it can be.
We were required to use CEE's in Florida even back in the 70's because of the lightning down there.