Here we go again, but not with a motor circuit this time.
215.2(A)(1) minimum size and rating - not more than 600 volts - general -
Feeder conductors shall have an ampacity not less than required to supply the load as calculated in Parts III, IV, and V of Article 220. The minimum feeder-circuit conductor size, before the application of any adjustment or correction factors, shall have an allowable ampacity not less than the noncontinuous load plus 125 percent of the continuous load.
85 continuous x 1.25 = 106.25
105 non continuous
106.25 + 105 = 211.25 This is minimum size conductor required
before adjustment factors and will be at 75C unless terminations are otherwise marked. This is the minimum size required by the termination temperature rating, the insulation temperature rating comes next. You make ampacity adjustments for insulation rating at 100 percent of load, but also at 90C (unless using other than 90C conductors) Again, the 125% factor for continuous loads is for the termination temp and is before ampacity adjustments.
85 cont + 105 non cont (both at 100%) = 190. Adjustments for insulation temp @ 90C will be based on a load of 190 amps.
I like to multiply the load by the reciprocal of the adjustment factors to come up with a minimum ampacity required instead of selecting a conductor, derating it then if it is too small doing it all over again with another size.
We have a factor of 1.25 (which is 1/.80) for an adjustment for number of conductors in the raceway.
We also have a factor of 1.04 (which is 1/.96) for an adjustment for ambient temperature.
190 x 1.25 x 1.04 = 247 amps is our minimum ampacity needed for a 90C conductor after accounting for needed adjustments.
247 @ 90C needs a 4/0 conductor which is good for up to 260 amps, and is not greater than the minimum size needed for termination temp @ 75C so we do not need an increase to the minimum size needed before adjustments.
4/0 90C conductor is the minimum size conductor needed for this application.
215.3 overcurrent protection -
...the rating of the overcurrent device shall not be less than the noncontinuous load plus 125 percent of the continuous load.
85 continuous X 1.25 = 106.25
105 non continuous
106.25 + 105 = 211.25
A 225 amp overcurrent device satisfies 215.3.
240.4(B) Overcurrent Devices Rated 800 Amperes or Less.
The next higher standard overcurrent device rating (above the ampacity of the conductors being protected) shall be permitted to be used, provided all of the following conditions are met:
(1) The conductors being protected are not part of a branch circuit supplying more than one receptacle for cord-and-plug-connected portable loads.
(2) The ampacity of the conductors does not correspond with the standard ampere rating of a fuse or a circuit breaker without overload trip adjustments above its rating (but that shall be permitted to have other trip or rating adjustments).
(3) The next higher standard rating selected does not exceed 800 amperes.
A 225 amp overcurrent device satisfies 240.4(B).