Are you asking which "X" leads are used to connect your 120 volt source ?
Is the transformer secondary single phase or three phase ? 240/120 ? 208/120 ?
In general for transformers, by convention, X means low voltage connections and H means high voltage.
However there are some manufacturers that do not follow this convention (in particular Current Transformers), instead they use H for primary and X for secondary.
So, you need to looke at the namplate wiring instructions and not just the terminal IDs.
The ANSI standard is for power transformers is: H = high voltage and X = low voltage.
But there is no guarantee this applies to your device, although it probably does because you are saying the voltage is 120/240V which is not a standard primary voltage designation.
What does your nameplate say for wiring?
Why do you care?