FWIW, batteries change impedance (a lot, sometimes) over time. On some medical cells, we'd measure it over the expected life of the cell, and it was a fairly accrurate predictor of end-of-life, esp compared to voltage under load. In this case, z (@about 200Hz?) would start to rise way before e would start to drop.
Can you PM me with more details as to not hijack this thread?
Thanks!