The transformer rated power is not important. You may check the cable in steady state load, but:
For instance: 3 cables laid underground at 30 dgr.C and 1.5 K.m/W, trefoil configuration,
50 sqr.mm Aluminum conductor cable 12/20 KV, xlpe insulation: maximum permissible current: 140 A [3400 KVA].
As ninjutsu said, you have to know:
-the short-circuit current [at least at RMU level].You may reduce it if you recalculate the short-circuit current at the supplied transformer terminal.
-fault clearance time [it will be better at the RMU main breaker]
-insulation [XLPE, EPR, PVC or else]
-conductor material [CU, AL]
-frequency [50 or 60 Hz]
For instance: 25 KA 1sec XLPE /CU 50 Hz the minimum conductor cross section will be 150 sqr.mm [300 MCM]. [X/R=10].