I'm with you Zee. I don't think there's any logical reason for it. Just a certain ingrained bias against ungrounded systems in this country, is my guess. I think that ungrounded PV systems are in fact a bit safer. To my mind an array that has a ground fault is dangerous regardless of whether it started as a grounded or ungrounded system. Also, when a ground-fault fuse blows then what do you end up with? ... An ungrounded system, that's what. 690 even requires a warning label on inverters that says this.
Ergo, to my mind, whatever is good enough for grounded systems should be good enough for ungrounded systems, and vice versa.
SolarPro, I think we all know that PV wire is more robust than USE-2. If it's that much safer, maybe the code should just require it for all PV arrays. It would cost us a bit more money but simplify our supply chains.
(Then there's the vendor that just shipped me a bunch of USE-2 that they had labeled 'PV Wire' on the box. But that's another issue...)