A quick search on Google I found this.
http://www.prioritywire.com/specs/Copper XHHW.pdf
1-877-611-5122
Priority Wire & Cable, Little Rock, AR PWC-2013
Copper XHHW-2 600V XLPE Insulation
Application:
XHHW-2 cables are primarily used for power distribution. XHHW-2 cables may be used in wet or dry locations, with ambient temperatures not exceeding 90°C. Voltage rating for RW90 cable is 600V.
Conductors:
XHHW-2 conductor is a compact soft drawn bare copper with class B stranding per ASTM.
Insulation:
XHHW-2 has abrasion, heat and moisture resistant cr
oss-linked polyethylene insulation XLPE.
FYI compact type wire is more common with aluminum conductors than copper.
Like I said for 4/0 XHHW copper you will need to check for availability.
The 3/0 XHHW for the neutral conductors does not need to be compact type.
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