Actually that's just a mistake, a very common one too. OFFICIALLY, 3 phase voltages should always be denoted as the higher number first, the lower second. So 480/277 is correct, 277/480 is not; 208/120 is correct, 120/208 is not. But in the case of 480/277, we always know what it means, there is no alternate interpretation. Where it can get confusing is in 240V, because if you say "120/240V" it officially means it is a SINGLE PHASE system, whereas "240/120V" would officially denote a 3 phase 4 wire delta center tapped system (although because the error is so common, it's best to just say "240/120 3 phase 4 wire").
Side note: I thought it interesting that the calculator refers to gold conductors. Can you imagine seeing 500kCMIL gold cable? I can, but not for long!