Thanks IWire. The NEC does not use the term hi and lo voltage.
And one of the most misquoted sections in the NEC is 300.3(C)(1). Read the FPN and section 90.3
Then read the title of Article 725 "The mother of all low voltage articles".
There are several articles in the NEC that deal with systems that operate below 50 volts.
See if you can find those and note the title does not include the term "Low Voltage". The code authors must of known this when the articles were written. By the way, one goes back to the 1930s.