I also have seen it using 600V wire.
I wonder though, once there was a new 20MW plant that I worked on and since it was a relatively unloaded plant for the first 6 months or so, the voltage ran at 605V, and I lost a lot of sleep thinking that the voltage was higher than the conductor ratings. The POCO didn't want to adjust the primary tap on the substation, so it ran a bit high for 6 months. I guess luckily, the 600V rating is a conservative value from the manufacturer and the system seems okay.