You have used the term "secondaries" in you original post which leads me to think you may be using two transformers, one to step the voltage up at the source, and one to step it down at the end of the 800 ft run. If that is the case, the are particulars that need to be addressed in terms of OCP and grounding, but the bottom line is kwired's statement that you can't gain power.
KW is KW. One you determine the load you wish to supply in terms of KW, any and all transformers will need to have at least that same KW rating, but in your case, the wire size limits your load to approximatekly 15 kw.