There is no such thing as an “80% rated breaker”. All breakers are rated at 100% of their stated load. A 100A breaker will never trip when loaded to 100A.
The reason we THINK of them being “80% rated” is because of the INDIRECT rules of how they must be used, resulting it how the mfrs use them and test them. It’s indirect based on this:
1) CONDUCTORS must be sized for 125% of the CONTINUOUS load, based on 3 hours being considered continuous.
2) BREAKERS are sized to protect the conductors.
3) the INVERSE of 125% is 80%, meaning if I know a conductor is rated for 100A and I want to size it for a continuous load, 100 divided by 1.25 = 80A, ergo 80%.
4) So if you have a load that is 80 A continuous, you size the conductors at 125% of that, which will be 100A and since a breaker protects the conductors, you use a 100A breaker.
5) then because the breaker mfr KNOWS this, when they rate how you use a breaker in a panel, it is based on it never being loaded at more than 80% continuously, because you would not be able to do that to the conductors. So the heating of the breaker, when crammed into a panel with other breakers, is accounted for in the listing of them in that panel.
A ”100% rated breaker” is the same breaker, but listed for use under the same restrictions in which you can use and terminate (another issue) the cables at 100%. What you will find is that the only way to use a 100% rated breaker is as a stand-alone enclosed breaker or as a main breaker in switchgear, MCCs etc. where there are no other breakers adjacent to them and usually connecting to bus bar.