The NEC does not allow you to parallel dissimilar conductor sizes. By parallel, it means both/all paths have the same origin device, and the same destination device.
This is true even if it would be code-compliant to scrap all but the smallest size, and have it carry the full load. If you are going to add a parallel conductor whether to curtail voltage drop or increase the ampacity, it has to be the same size as what it is paralleled with.
Dissimilar sizes & characteristics will mean that current will not divide uniformly among the paths in parallel, which means one path will systematically carry disproportionately more than its share of the current. To avoid complicating the matter and needing to calculate exactly how many amperes are carried on each path, the NEC ruled out dissimilar conductor sizes in parallel altogether.
Physics-wise, if you built dissimilar conductors in parallel despite not being code-compliant, current would divide in proportion to the conductance of each path. Conductance defined as 1/resistance. From the first order factors alone, conductance is proportional to the KCMIL, and inversely proportional to the length.