4 cal/cm? is HRC (Hazard/Risk Category) 1 which would require arc-rated clothing. HRC 0 requires nonmelting or natural fiber long sleeve shirt and pants (4.5 oz/yd?). There is no incident energy associated with HRC 0, but 1.2 cal/cm? would be implied as the upper limit.
NFPA 70E doesn't really say to use HRC 0 under the 208 V, 125 kVA exception, only that an arc flash hazard analysis is not required. I would assume that you would then go by the task tables which have HRC 0 minimum, but HRC 1 for voltage testing.
Assuming HRC 0 could also be justified because the basis for the exception is IEEE 1584 which says that
The arc-flash hazard need only be considered for large 208 V systems: systems fed by transformers smaller than 125 kVA should not be a concern.
In fact, you could interprete this to mean that there is no hazard and PPE requirements are for where hazards are present. All in all, I think HRC 0 PPE would be acceptable, but then I'm not an OSHA inspector investigating an accident.