If one has ever taken the UL classes/seminars, the 75C requirement has been discussed in detail during the classes/seminars.
The termination location is not the sole portion of the circuit to be required to be rated. All the components of the circuit are. As of now, I am not aware of any enclosures rated higher than 75C. Just changing a termination to 90C rating is not sufficient to change the circuit rating. The bus, terminations (both sides), enclosure, conductors, etc... Adding onto the conductor does not satisfy the change necessary to the whole circuit in regards to the 75C requirement.
This is why I brought up making the transition beyond the confines of the enclosure.
SQD has a good PDF in their site, that explains this very well.
A clip from said document....

Link to document: http://ecatalog.squared.com/pubs/Electrical Distribution/0110DB9901R2-02.pdf