As long as it's a bolt in breaker or has a retaining clip or screw if it's a snap in, it should be compliant.
I have never noticed a back fed rating of a breaker. I am not sure why that would be necessary.
I think that by using a breaker that has "line" and "load" terminals as a back-fed breaker, you are violating the listing of the breaker by connecting "line" to the "load" terminals. Maybe its not so much that the breaker is listed as "back-fed" as that it is not listed for "line" and "load."
I remember reading about that issue on the MikeHolt website before. If I could find a link to the article, I'd post it.
That's a specification, not a requirement."main lug only panel"
Have a 42 space breaker panel main lug only, 208/120 3 phase 4 wire, rated for 250 Amps (Siemens). A 3 phase 90 Amp breaker was installed at the bottom left and is being used as the main breaker. Is this acceptable standards in a commercial application?
I don't have a problem with it, with the details given. It seems a little odd, but it could well be code compliant.