The basic rule I use in my classes:
Other than loads shown in 240.4(G) {air conditioners, motors, etc}\
1. Calculate your load (name plate, Art 200, etc)
2 Select a conductor with an ampacity adequate for that load (after any derating, etc)
3.Select an overcurrent device to protect the conductor and the load applying the rules in Art 240.4
Example" 59 amp load (non-continuous)
210.19 (and 215.2 for feeders) require the conductor ampacity be equal to or greater than the load so you need a conductor with an ampacity of 59 amps after any adjustments (fill, ambient, etc.)
For 59 amps that would normally be a #6 with an ampacity of 65 amps @ 75° (#4 NM due to the 60° rating)
You would then select an overcurrent device based on the 65 amps. 240.4would allow the "next size up rule" so a 70 amp breaker could be used.