My understanding is that you have to use the _lowest_ temperature rating of everything connected in the region being considered.
If you have 90C wire connected to a 75C terminal, then at the point of that connection you need to use the 75C rating to determine ampacity
If somewhere else along the length of the wire it is subject to different surrounding conditions (say higher ambient temperature or derating for other current carrying conductors), then you use the temperature ratings of the components in that region. So the 90C conductor _in the conduit_ is derated from 90C, even though elsewhere it is connected to a 75C component.
Since the current is the same everywhere along the wire, the minimum ampacity determined at every point along the wire is the one that holds.
There is clearly a hole in this understanding, and I don't see an answer in the code: how much separation is required between 'regions'. Copper is a good conductor of heat; if the wire is at 90C inside the conduit (it likely is not, but it could get to that temperature), then how much wire is required before you hit the 75C termination.
-Jon