The basic concept is that you must provide enough power to handle 100% of the connected load, plus an occasional 25% kicker for specific loads, UNLESS the NEC gives you a specific demand factor that permits you to provide a lesser amount of power. There is, for example, a demand factor for receptacles in non-dwelling units, and this might be applied to a portion of your classroom load. But there is no demand factor for a "modular classroom" as an entity unto itself. You need to do a load calculation, as nakulak has said.