171118-2121 EST
... reason is for this effect.
Can become a very complicated subject.
50 years ago I was shown a piece of a fly wing embedded in the paper of a paper/foil oil filled capacitor and was told that imperfections were the main reason volts/mil dielectric withstand decreased with thickness.
As mentioned in your referenced, once polymers come into the equation the question of electric fields and length of polymers comes into play, but imperfections still are the main reason. Damage due to assembly is alos considered and imperfection.
Occasionally, the converse is true. Had 3 kapton insulation layers in a high voltage high frequency (1 kV, 100 kHz) transformer. Unfortunately the vacuum potting procedure was flawed and there were air gaps between a layer next to the winding . A stress riser led to partial discharges eating thru the outer layer (and thru wire insulation), and the other 2 kapton layers 'zippered'. In this case, one thicker dielectric would have probably not failed as kpotting would have been able to eleiminate the air voids, but that is a secondary effect.