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I believe from general information I have seen in the past that Sahib's comment is probably correct. I don't know what the reason is for this effect.
It may result from a nonuniform field intensity, and/or imperfections. See BertHickman's comment at
http://cr4.globalspec.com/thread/69395/Does-Dielectric-Strength-Depend-On-Thickness .
Magnet wire for high power compact motors have "enamel" insulation made up of many separate layers. Like 15 layers adding up to 50 microns (about 0.002") in total thickness. A major problem with magnet wire is that it has to be bent. This mechanically stresses the insulation.
The following reference may not relate, but is of interest:
https://en.wikipedia.org/wiki/Partial_discharge .
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