The temperature restrictions in the Code for terminations have nothing to do with how you figure ampacities over the length of the circuit. Here's a contractor-focused review of both.
If we don't do anything else in this trade, we all select, install, and terminate conductors. We've seen many misconceptions over the years, and they usually involve confusing the middle of a wire and the end of the same wire. Now, you probably think you know the difference, and you do. Just be sure you keep that difference in mind when you select your conductors.