That's not exactly what 250.68 addresses but to answer your question, black iron gas piping can be considered bonded by the equipment grounding conductor connected to a gas appliance or by other means spelled out in 250.104(B) if the appliance ground is not present. If you do bond it with a jumper to another electrode or the service, it can be connected at any point in the system although some inspectors like to see it at the water heater.