I know according to 250.66(A) and (B) that the largest GEC to a rod, pipe or plate is #6 copper or #4 alum and to a CEE it is #4 copper. Where does table 250.66 apply? Just connections to metal water pipe and building steel?
You would use Table 250.66 for example if you run a GEC from the service to a water pipe or structural metal building and from that point to a rod, pipe or plate, that portion of the GEC between the service equip. and the water pipe must be a full-size conductor per Table 250.66. ie: 3/0 awg ungrounded copper conductor would need a #2awg GEC. Then from the water pipe to the rod would not be required to be larger than #4awg for CEE or 6awg for rod.
I see no problem with the logic, but a couple of problems with the numbers.
A 3/0 cu service conductor grounding electrode conductor according to 250.66 could be as small as #4 cu and the ground rod exception allows a reduction to a #6.
Has 250.66 in 2011 code changed from 2008? Don't have new book yet.