352.24 Bends ? How Made. Bends shall be so made that the conduit will not be damaged and the internal diameter of the conduit will not be effectively reduced. Field bends shall be made only with bending equipment identified for the purpose. The radius of the curve to the centerline of such bends shall not be less than shown in Table 2, Chapter 9.
I can not imagine that you have a torch that is identified for the purpose or that you can use a torch without scorching the outside of the conduit. Additionally, if you can't assemble a conduit without the conductors enclosed, how can you work a piece of PVC with the conductors enclosed? Does anyone know that the conductor insulation will not be damaged when the temperature exceeds the pliability point of the PVC?
In my opinion, this can not be done while protecting the conductors. Pull the conductors out, do the work correctly, and pull in new conductors.