NFPA 820 is specific for Fire Protection in Wastewater Treatment and Collection Facilities. It refers to both NFPA 496 and 497. Chapters 4, 5 & 6 have extensive Tables describing proper electrical area classification. Chapter 9 is for the applications of ventialtion
Only if the Tables in Standard 820 don't apply should anyone attempt to use NFPA 497 for wastewater applications. The NFPA 820 Technical Committee has already made most of the judment calls in the Tables.
If the OP wants to use ventilation as a basis, NFPA 496 is appropriate for evaluating ventilation systems by other than "natural" means.
Except for Articles 510-516, anyone who attempts to classify a location directly from the NEC, doesn't understand what they are doing. See Section 500.4(B) and especially FPN No.1. FPN No.2 also specifically references NFPA 820.