Less than 100A. Unless you fit conditions below, you must size based on 60C due to terminations. You may then use the derate of that size conductor based on the particular insulation, as augie47 suggested.
110.14(C)(1)(a)
(1) Equipment Provisions. The determination of termination provisions of equipment shall be based on 110.14(C)(1)(a) or (C)(1)(b). Unless the equipment is listed and marked otherwise, conductor ampacities used in determining equipment termination provisions shall be based on Table 310.15(B)(16) as appropriately modified by 310.15(B)(7).
(a) Termination provisions of equipment for circuits rated 100 amperes or less, or marked for 14 AWG through 1 AWG conductors, shall be used only for one of the following:
(1) Conductors rated 60°C (140°F).
(2) Conductors with higher temperature ratings, provided the ampacity of such conductors is determined based on the 60°C (140°F) ampacity of the conductor size used.
(3) Conductors with higher temperature ratings if the equipment is listed and identified for use with such conductors.
(4) For motors marked with design letters B, C, or D, conductors having an insulation rating of 75°C (167°F) or higher shall be permitted to be used, provided the ampacity of such conductors does not exceed the 75°C (167°F) ampacity.