Here is another general 2002 NEC perspective.
If 4160vac + rated insulation meets NEC Tbl 310.63-4, it can be used for svc.entrance 230.41, and spaced using Tbl. 310.60. Other requirements make some MV cables in above-ground EMT possible; NEC 110.36, 300.35-37 & related areas. Be careful, since 230.3, 695.6, etc., wont allow it without industrial-supervision exceptions. Local codes, AHJ's, and building specs, would also need to be checked.
Couldn't find how above-ground conduit access is restricted or marked for high voltage? Would hate to work around this blindly, since higher-voltage insulation leaks to conduit are less likely to trip OCD's.