Additive in what regard?
By that I mean do you want to look at this from an electrical code standpoint? If so, I think you just have to go by the wires listing. Adding more insulation won't do anything to increase the listed voltage rating, so no, you would still have a 600V wire. Also note that the nylon jacket on most wire gets scuffed or torn when the wire is pulled into a conduit, so the nylon jacket on most wire is more for oil and gasoline resistance, and doesn't really help the voltage rating that much.
Or from the physics standpoint? How much voltage can we really expect the combination of wire insulation and a PVC tube to withstand?
From that standpoint I'm going to guess that maybe its even higher than the sum of the two voltage ratings. Like Charlie, I will admit I could be wrong.
But look at this chart:
https://www.anixter.com/content/dam.../anixter-insulation-levels-wire-wisdom-en.pdf
And notice that the insulation on a 15KV line is not even twice the thickness of the insulation on a 5KV line. So doubling the thickness gives 3 times the voltage insulation. Similar thing with 25KV. Five times the voltage of 5KV, but the insulation thickness is only about 3 times as thick.
So its not a linear relationship. A layer of 600V insulation over a layer of 600V insulation would double the thickness, and might give you around a 1800V insulation level.
However, there are also so notes about 0-2000 Volts, and that may be a different situation than the higher voltage KV rated cables.