I believe so, and yes. You can use any two lines for line-to-line-only loads, also, but all 2- and 3-pole breakers must be rated 240v, and not 120/240v.
Barring various what-if's, I think you're correct.Please inform me if I am wrong on that assumption.
I think its best to setup an equipment panel for the three phase and a single phase panel for everything else.
It will save lots of future problems, and is very inexpensive to do