IMHO table 310.13 tells us where a particular type of wiring can be used, and lists MTW for wiring per NFPA 79 and in Machine tools per article 670.
On the other hand, the text of 310.13 (2002) says 'These conductors shall be permitted for use in any of the wiring methods recognized in Chapter 3......', and if you look at the entry for SIS wiring it says 'switchboard wiring only', but the entry for MTW doesn't say 'Machine tool wiring _only_'. So perhaps it is allowed.
One caution: in my experience, wire that says 'MTW' only is more finely stranded than wire that is rated THxx/MTW; this may cause problems with respect to the ratings of terminals.
-Jon