Assume a 4160V System. If the system is solidly grounded I assume that the voltage to ground to be used for determining the proper working distance is 2400V. If the system is a delta I have always assumed that the voltage to ground to be used 4160V since one phase could be grounded and the system would not experience faults - I not sure that this is correct and would like verification.
The real question is for resistance grounded systems. When a phase goes to ground on these systems the phase-to-ground voltages of the other two phases elevate to the phase-to-phase voltage much like an ungrounded system. What voltage to ground should be used in determining the proper working distances? A ground fault on low resistance grounded system will typically be relayed to cleared in 10 seconds or less where the high resistance grounded system may be energized for a prolonged period of time. I'm unclear whether this distinction would make any difference in the answer.
The real question is for resistance grounded systems. When a phase goes to ground on these systems the phase-to-ground voltages of the other two phases elevate to the phase-to-phase voltage much like an ungrounded system. What voltage to ground should be used in determining the proper working distances? A ground fault on low resistance grounded system will typically be relayed to cleared in 10 seconds or less where the high resistance grounded system may be energized for a prolonged period of time. I'm unclear whether this distinction would make any difference in the answer.