The following is a link for a Liebert UPS 30kva. They call for a 50A OCD on the primary with 480 in and 120/208 out. Doing the calcs for a transformer 30kva/480x1.73= 36A x 125%=45.2A round up to 50A OCD. Seems that the secondary is OK since you can go to 250% OCD if you have primary OCD at 125%, 30kva/208x1.73=83.3Ax125%=104A round up to 125A.
The input current may be larger to allow for the battery charging circuit, depending on the arrangement of the system.
That being said, if you go with the listed manufacturer's specs I don't see how you could go wrong. Just watch the wire size on the secondary, #4 AWG I believe is too small. Assuming you do not have a large harmonic load on the unit and do not have to count the grounded conductor, you would be at #2AWG or you would have to go with 1/0 if you have a majority of harmonic loads.
http://www.liebert.com/product_pages/ProductTechnical.aspx?id=79&hz=60