If your PLC panel has 480 volt inside PPE is required. If the PLC only has 120 volt the PPE would be dependent on what you are doing. If your working on the 110V stuff then voltage rated gloves are needed. If your just hooking up the cable to look at the PLC program and that action does not put you in proximity of thw 110 volt, then the PPE may not be needed. Of course this assume you are opening the cabinet door to access the PLC.
The big question I have, are your folks qualified to know what the voltages are in side the PLC cabinet? This may sound trite, but we recently had one of experiened guys poking around in a new IEC designe cabinet not knowing it had 480 volt running thru out the cabinet. Luckly one of our eletrcial folks stopped him before he got hurt. We have since installed 480 volt warning labels but it just goes to shows that expereince does not realet to qualified.
To err on the conservative side, I would make external connections for the PLC hook up and avoid opening the door.