Justin, Article 300.22(B) explains the wiring methods allowed, and pvc is not listed
(B) Ducts or Plenums Used for Environmental Air Only wiring methods consisting of Type MI cable, Type MC cable employing a smooth or corrugated impervious metal sheath without an overall nonmetallic covering, electrical metallic tubing, flexible metallic tubing, intermediate metal conduit, or rigid metal conduit without an overall nonmetallic covering shall be installed in ducts or plenums specifically fabricated to transport environmental air. Flexible metal conduit shall be permitted, in lengths not to exceed 1.2 m (4 ft), to connect physically adjustable equipment and devices permitted to be in these ducts and plenum chambers. The connectors used with flexible metal conduit shall effectively close any openings in the connection. Equipment and devices shall be permitted within such ducts or plenum chambers only if necessary for their direct action upon, or sensing of, the contained air. Where equipment or devices are installed and illumination is necessary to facilitate maintenance and repair, enclosed gasketed-type luminaires (fixtures) shall be permitted.
Rick