Black shoe polish makes them look great, know for a fact this is done. And with rare exception I believe this is the norm, unless as Zog says, you get hard data from a reputable firm.
Silicone spray is cheaper and easier to use. Puts a nice shine to the phenolic.
To back up what Zog says, the equipment necessary to perform the right tests on the breakers is VERY expensive, as are the employees with the right skill set and experience to do it. When you see a "refurb" breaker that is too cheap to be true, it probably is a silicone job; ohmmeter to the line and load terminals, quick spritz of silicone spray, box it and sell it. If they spent more than 30 seconds "refurbing" it, they spent too much in their opinion. They really should just call those "recycled" breakers, not refurbished. I know of a company that does both; the recycled breakers are sold for a lot less than the refurbished ones, but they make sure everyone knows the difference. Not all of them are that conscientious.
Good houses disassemble the breakers, clean the insides, check the mechanisms and replace worn components, do an injection test on the sensors, reassemble, test again and reseal them
with their name on them clearly identifying them as refurbished and tested, along with a test report. Anything less than that is a recycle.