For those who might be confused, table 310.15(B)(7) appears in the 2011 NEC. In the earlier versions, the table was 310.15(B)(6).
I agree that you can't get twice the ampacity by using two parallel conductors, because you don't know the ampacity of a single conductor. This is not an ampacity table. All you know is that we are allowed, under certain limited circumstances, to use conductors that would be too small, if we stuck with the ampacity values in table 310.16.
That said, I submitted a proposal for the 2011 NEC, adding words to 310.15(B)(6) that would explicitly forbid paralleling. The CMP disagreed with me, saying they intended us to be able to do what the OP suggests doing. They went further, saying the present wording allows this. I plan to challenge them again for the 2014 NEC. I still say that nothing in the NEC says we can use two or more sets of conductors that are listed in table 310.15(B)(7) for services and feeders of twice the tabulated ratings.