3 phase kVA = amps * sqrt(3) * V_line-to-line / 1000
3 phase kVA = 100 * sqrt(3) * V_l-l / 1000 = 0.1732 * V_l-l
But, as iwire pointed out, they don't make a single transformer that does that. You would think somebody might come up with a a 120/208 version, but I don't recall seeing one.
The problem with single phase to three phase, is that you need at least two voltages that do not lie along the same axis. Most single-phase is from a center-tapped transformer, and the neutral point lies along the vector of the line-line voltage.
The 120/208 has a neutral point that does not lie on the vector of the line-line voltage and is a candidate for deriving three phase. I don't know that anybody actually does it.