Why would it be any different than just having a window as far as color temperature goes?
Several things come to mind.
A Solatube is typically ceiling mounted so it is next to the lights. Windows are generally farther away from the lights. Easier to compare things that are close together. Also, windows are typically bright enough that any lights adjacent to the windows are very dim by comparison and any color difference is not overly noticeable.
A Solatube looks like a light fixture, lens and all. Windows, not so much. People see a Solatube and think it is a luminaire. Expectations are different from what is normal for a window, and people tend to see what they expect to see. Even if the light through a window and through a Solatube have exactly the same color temperature the brain "sees" them differently.
A Solatube in effect brings in light from directly overhead. Windows tend to be shaded by structure (to reduce heat gain) or are on the north to provide indirect light. Most windows are tinted, coated, and/or have blinds or curtains to control the light. Solatubes may have a damper, but the damper does not normally change the color or color temperature of the light like tinting or reflecting off colored curtains does.
In the last commercial building I was in that had Solatubes the lights were all Lithonia RT5 with 3500K lamps. Areas with no Solatubes looked normal for an office. Light through the windows was either diffused or was patterns that were expected (rectangles or trapezoids relatively low on the walls and on the floor) and the light through the windows did not make the fluorescents look brownish in those areas. In areas with Solatubes there were bright white spots on the floor directly under the Solatubes, and having blue-while Solatube lenses next to the fluorescents made the fluorescents look dirty. The tenants did not like the lighting in the areas with Solatubes but thought non-Solatube areas were well lit. The Solatubes were added by the architect, not the lighting designer, and there were not enough Solatubes to allow the fluorescents to be turned off and still have the workspaces usable.
To get the fluorescents and Solatubes more alike in color temperature the options are to raise the temperature of the fluorescent lamps or lower the temperature of the Solatubes. Most of my clients want warmer lamps, so changing the Solatubes is the better option.