Because it would be a receptacle, no. For another small load it might hve been ok. 210.19(A)(4) Exception(c).1. Existing 50amp, 240V. outlet for a oven. Don't need 240v. just a 120v. outlet for a gas stove.
Can I tap off the 240v. outlet with 12awg. for a outlet for the stove?
2. 12awg homerun ran to a switch box. 14awg. wire used just for switch legs.
OK?
1. A. does the circuit for the oven have a neutral and an equipment ground?
1. B where are you going to put the overcurrent device required at the end of the tap. Keep 110.26 in mind.
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If a 210.19 branch-circuit tap, no supplemental OCPD required.
OP mentioned a gas cook top, this is going to have a cord on it from the factory and 210.19 A(3) is not going to apply