Theoretically, if you could find terminations, devices, and equipment enclosures all rated for 90C you could use that column for basic sizing of the circuit as long as the wire type had a 90C column and it was not otherwise restricted (as NM is).
But it just does not happen.
If there were a really serious engineering issue that was solved by running wire at the 90C rating you could use a junction box at each end with 90C rated terminations and switch to larger wire to actually connect to your devices.