According to NEC Table 450.3(B), Art.215.2.1(a) and 240.4,
in my opinion, 125% of rated current will be 65 A primary and 136 A secondary. A 70 A breaker for primary and 150 A for secondary and as per Table 310.15(B)(16) 4awg primary and 1/0 secondary as a minimum cross section area for copper conductor 75oC insulation.
You have to check the voltage drop-no more than 5% total [3% per feeder.] Art.215.2.1(b)
Informational Note No. 2.