Nikola Tesla, the discoverer of polyphase currents and inventor of the induction motor, employed two-phase current, where the phase difference is 90?. This also can be used to create a rotating magnetic field, and is more efficient than single-phase, but is not quite as advantageous as three-phase. Two-phase power was once rather common in the United States, where Tesla was important in the introduction of AC, but has now gone completely out of use.
Two-phase can be supplied over three wires, but there is no true neutral, since the phases are not symmetrical. However, it is always easy to double the number of phases in a transformer secondary by making two secondary windings and connecting them in opposing phases.