Re: uf cable in conduit ?
Free air is the worst case for dissipating heat, or more correctly; the efficient removal of heat from a conductor.
The reason for ampacity to be increased is due to the elevated heat, in free air, is no problem. It has nothing to do with cooling effects of air, allowing more heat.
Glass, and wood, are better heat sinks than air.
Conductors will run cooler inside a metal conduit than direct burial. When direct buried the dirt dries out around the cable and forms an insulator, the thermal conductivity decreases.
When designing heat sinks, the best metal is silver, W/(m ?C) is 410. Copper is 390. These are the same as electrical conductivity (S/m)