You can replace a non grounding switch with a grounding style w/ no egc present- 404.9(B) exception.
As for when non metallic screws are needed- Here is an excerpt (from 404.9 Exception #1 to (B) ) :
......A snap switch wired under the provisions of this exception and located within 2.5 m(8 ft) vertically or 1.5 m (5 ft) horizontally of ground or exposed grounded metal objects shall be provided with a faceplate of nonconducting noncombustible material with nonmetallic attachment screws, unless the switch mounting strap or yoke is non metallic or the circuit is protected by a ground fault circuit interrupter."