The requirement for the project that i am working on is to use XHHW-2 90C conductors and i am using the ampacity table under 90C in 310.15. so, i am calculating the change in resistance value at 90 C using the value at 75C from table 9.
OK, say you are using 1/0 Al, which has a 75C ampacity of 120A and a 90C ampacity of 135A.
If you are using it with at most 3 CCCs in a conduit or cable, at an ambient temperature of 30C, and you have a continuous 120A load, then the operating temperature may be as high as 75C, and using the 75C resistance is appropriate. This is an application where you would have been fine with a 75C rated insulation temperature, so obviously it won't be getting above 75C.
Whereas as if you have the above conditions but in the controlling case for voltage drop you know the current will only be 100A, now you know that the conductor operating temperature will be at most 30C + (100/120)^2 * (75C - 30C) = 61C, so if anything you could adjust the resistance down from the 75C resistance.
Conversely, if you are using the conductor with say 6 CCCs in a conduit or cable, and the ambient temperature is elevated so you have a temperature correction factor of 0.9, now your ampacity is limited to 135 * 0.8 * 0.9 = 97A. If it is really carrying 97A, now the conductor temperature could be as high as 90C, and correcting the resistance to a 90C value would be appropriate.
Cheers, Wayne