The danger to a human from electricity is the amount of current passing through your body. Your body acts a resistor (whose characteristics widely depend on if you are wet or not, breaks in your skin, insulation of your shoes, etc), which when applied to Ohm's law you can see that higher voltage will result in more current (or as you put it, more electrons being pushed through your body). It only takes on the order of tens of mA to cause injury, so even 12 Volts can be dangerous in the worst case conditions. Having said that, NFPA 70E considers voltages less than 50 V to be generally permissible to work on live. There are differences in how AC or DC effects a person. Your skin acts as a capacitor, which has decreasing impedance with increasing frequency, therefore AC works against you in that case. However, since AC crosses the zero voltage line 60 times a second, you are more able to 'let go' in the case of shock.