I know there seems to be no rhyme or reason to it but there must be something. Gutter space? The real question is why are non-CTL breakers more expensive? And once the 42 circuit limit went away this all seems to be nonsense.
My thoughts
They sell and have been selling many more the CTL units. To make a production run of non CTL might mean resetting the production line for whatever is different for a more limited run of product than normal. There probably isn't as much demand for this product so both Schneider as well as supply places aren't going to carry as big of a stock of said product either.
LED lighting has mostly taken over fluorescent tubes, but we had same thing there. Remember how much more expensive tubes that were 2,3,5,6,7 feet in nominal length were compared to 4 and 8 foot tubes? The 4 and 8 footers were manufactured and sold in much higher quantities even though they might have taken more raw materials than some the others.
I think the information on label that prompted OP to ask about is likely just an error, maybe even by people that do not read/write the English language very well. with the 24/24 example they don't even need some of what is on there but is apparently a boiler plate type of thing where they only plug in information that does change from one product to another.