Depending on the application you might need to use the 90? C, 75? C or 60? C column for THHN. Do you have a specific example of what you're trying to size?
Yes you use the 90 deg. col.for derateing thhn but remember when you are sizeing the wire for a ckt. you must know the rateing of all parts in the ckt..If the breaker or equipment is only rated for 60 deg. than you must use that column.