You can estimate the voltage level of that cable by measuring the thickness of the insulation. 200 MILS for 15 kV, 260 MILS for 25 kV (if I remember correctly) or thereabouts depending if it's 100% of 133% insulation. All of the insulation thickness is standardized based on the dielectric strength of the material versus voltage level. So that's why it's always the same.
Also, as Charlie mentioned, you can differentiate between XLPE (cross linked polyethylene) and EPR (ethylene proplyene rubber) by the color of the insulation. XLPE exhibits that semi-transluscent color while EPR looks more like standard orangish rubber. EPR can reach higher temperatures at the cost of greater dielectric losses, while XLPE exhibits less dielectric losses, but is typically rated 15 C less than EPR (which means lower ampacities). Like everything else, the differences are a trade-off: lower line losses versus higher ampacities.
The concentrics, if they're solidly bonded (i.e., grounded at multiple locations, which they typically are), will carry neutrals currents for the cable system.
Higher voltage, solid dielectric cables with concentrics (i.e., greater than 69 kV), however, will almost never solidly ground those neutrals due to the loss in ampacity. Most high voltage cable installations will either single point bond or cross bond those neutrals to eliminate the induced current on those neutrals, which in turn significantly increases ampacity.
If you've ever seen a high voltage, solid dielectric cable installation and notice the neutrals on one end are connected to a voltage arrestor at the riser, you'll know the system is single point bonded and for very good reason since you can lose 20% or more ampacity simply because of the induced current on the neutrals. Also, most high voltage solid dielectric cables (greater than 69 kV) are almost ALWAYS XLPE or PAPER/OIL/PIPE TYPE (even though EPR is rated higher in temperature) simply because of high dielectric losses of EPR.
EDIT: sorry, the bulk of existing high voltage UG cable installations are pipe type, high pressure, paper insulation, oil filled cables (HPOF), but a lot of the newer installations are solid dielectric (XLPE) because it's cheaper and performs comperably.