It depends on the starting ambient from the Ampacity table that you are using.
Tables 310.15(B)(16) and (B)(17) are based on a 30degC ambient. You would use 310.15(B)(2)(a) for temperature correction.
Table 310.15(B)(18), (B)(19) and (B)(20) are based on a 40degC ambient. You would use 310.15(B)(2)(b) for temperature correction.